Redox-Neutral Cyanoalkylation/Cyclization of Olefinic 1,3-Dicarbonyls with Cycloketone Oxime Esters: Access to Cyanoalkylated Dihydrofurans,The Journal of Organic Chemistry

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Redox-Neutral Cyanoalkylation/Cyclization of Olefinic 1,3-Dicarbonyls with Cycloketone Oxime Esters: Access to Cyanoalkylated Dihydrofurans
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2018-03-20 00:00:00 , DOI: 10.1021/acs.joc.8b00271
Jia-Yu Zhang ₁ , Xin-Hua Duan ₁ , Jun-Cheng Yang ₁ , Li-Na Guo ₁

Affiliation

Metal-catalyzed cyanoalkylation/cyclization of olefinic 1,3-dicarbonyls with cycloketone oxime esters has been developed under redox-neutral conditions. This protocol provided a straightforward approach to diverse cyanoalkylated 2,3-dihydrofurans via a tandem ring-opening/addition/cyclization process.

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