Trifluoromethanesulfenamide reagent, initially designed as electrophilic reagent, can be considered as a trifluoromethylthio anion source in presence of tetrabutylammonium iodide. Herein, we report the reaction of trifluoromethanesulfenamide with organoselenocyanates to prepare under mild conditions compounds bearing a new fluorinated group, namely SeSCF₃.

中文翻译：

---

用三氟甲烷亚磺酰胺试剂对有机硒酸酯进行亲核三氟甲基硫醇化：获得含CF ₃ SSe的化合物

最初设计为亲电试剂的三氟甲亚磺酰胺试剂，在存在四丁基碘化铵的情况下，可以视为三氟甲硫基阴离子源。在这里，我们报告三氟甲亚磺酰胺与有机硒酸酯的反应，以在温和的条件下制备带有新的氟化基团，即SeSCF _3的化合物。