The present research reports on a successful strategy for the modification of a cobalt-containing metal-organic framework (Co-MOF-74 aka Co-CPO-27) with NDHPI for enhanced catalytic activity in the aerobic oxidation of alkyl-benzenes under mild reaction conditions. We present here the synthesis and characterization of the [email protected] composite. The experimental results show the successful incorporation of NDHPI molecules into the Co-MOF-74 metal-organic framework. The application of the [email protected] composite in the heterogeneous solvent-free oxidation of toluene with molecular oxygen as primary oxidant showed a high catalytic performance with 16% conversion and >30% selectivity towards benzoic acid in 2 h at 100 °C, O₂: 1.6 MPa.

本研究报告了用NDHPI修饰含钴金属有机骨架（Co-MOF-74 aka Co-CPO-27）的成功策略，以提高轻度反应下烷基苯的需氧氧化的催化活性。条件。我们在此介绍[受电子邮件保护的]复合文件的综合和特征。实验结果表明，NDHPI分子成功地掺入了Co-MOF-74金属-有机骨架中。[电子邮件保护的]复合材料在分子氧作为主要氧化剂的甲苯非均相无溶剂氧化中的应用显示出高催化性能，在100°C，2 h的条件下，在2小时内转化率为16％，对苯甲酸的选择性> 30％。₂：1.6MPa。