Corrosion Science ( IF 7.4 ) Pub Date : 2018-03-20 , DOI: 10.1016/j.corsci.2018.03.032 Yan-qi Wang , Gang Kong , Chun-shan Che , Tian-yu Weng , Zi-wen Sun
The influence of Mg addition on the corrosion behavior of Zn-x%Mg (x = 0.5, 1.5 and 3) alloys in saturated Ca(OH)2 solution was investigated with pure zinc as a reference. The Zn-Mg alloys were passivated but less resistant to corrosion. Mg alloying caused more negative corrosion potential of the Zn-Mg alloys and inhomogeneity of the passivation layer. Alternately preferential dissolution of the primary Zn-rich dendrites (PZD) and Zn-Mg eutectics (ZME) regions was observed. This was probably linked to the galvanic coupling between the PZD and ZME regions, and/or the Mg-rich passivation layer less resistant to corrosion than the Ca-rich passivation layer.
中文翻译:
Zn-Mg合金在饱和Ca(OH)2溶液中的腐蚀行为
以纯锌为参比,研究了Mg添加对Zn-x%Mg(x = 0.5、1.5和3)合金在饱和Ca(OH)2溶液中的腐蚀行为的影响。Zn-Mg合金是钝化的,但耐腐蚀性能较差。镁合金化导致Zn-Mg合金具有更大的负腐蚀潜能以及钝化层的不均匀性。观察到主要富锌树突(PZD)和Zn-Mg共晶(ZME)区域的交替优先溶解。这可能与PZD和ZME区域之间的电流耦合有关,和/或与富含Ca的钝化层相比,富含Mg的钝化层的耐腐蚀性更差。