Nondirected Copper-Catalyzed Sulfoxidations of Benzylic C–H Bonds,Organic Letters

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Nondirected Copper-Catalyzed Sulfoxidations of Benzylic C–H Bonds
Organic Letters ( IF 4.9 ) Pub Date : 2018-03-19 00:00:00 , DOI: 10.1021/acs.orglett.8b00615
Hao Yu ₁ , Zhen Li ₁ , Carsten Bolm ₁

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A copper-catalyzed sulfoxidation of benzylic C–H bonds by nondirected oxidative C(sp³)-H activation was developed. The process proceeds via sulfenate anions, which are generated by base-triggered elimination of β-sulfinyl esters and benzyl radicals. The functional group tolerance is high, and the product yields are good.

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