Cobalt(iii)-catalysed C–H allylation with vinylaziridines†,Organic Chemistry Frontiers

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Cobalt(iii)-catalysed C–H allylation with vinylaziridines†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2018-03-19 00:00:00 , DOI: 10.1039/c8qo00173a
Lingyu Kong _{1,

2,

3,

4,

5} , Bohdan Biletskyi _{1,

2,

3,

4,

5} , Didier Nuel _{1,

2,

3,

4,

5} , Hervé Clavier _{1,

2,

3,

4,

5}

Affiliation

A cobalt-catalysed C–H allylation of aromatic and heteroaromatic compounds with vinylaziridines is described. This transformation occurring under mild reaction conditions proceeds through C–H activation, carbon–carbon double bond insertion and β-nitrogen elimination. Its scope and limitations have been investigated and a synthetic application of products has been achieved.

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