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Effect of CeO2 on oxidation and electrical behaviors of ferritic stainless steel interconnects with NiFe coatings
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2018-03-19 , DOI: 10.1016/j.ijhydene.2018.02.178
Peng Fei You , Xue Zhang , Hai Liang Zhang , Hui Jun Liu , Chao Liu Zeng

Ferritic stainless steels are promising materials for application in interconnects of solid oxide fuel cells (SOFC). The present problems to be solved urgently for using ferritic stainless steels as interconnects are their rapid increase in electrical resistance and the cathode poisoning caused by evaporation of chromia. In the present study, the NiFe and NiFeCeO2 alloy coatings have been electro-deposited onto 430 stainless steels (430SS). During oxidation at 800 °C in air, an outer dense NiFe2O4 layer and an inner protective Cr2O3 layer have thermally grown on the coated samples. The NiFe2O4 layer retards the outward migration of chromium effectively. The addition of CeO2 reduces the growth rate of Cr2O3 and decreases the number of pores near the oxide scale/alloy interface. Moreover, a higher electrical conductivity has been achieved by the addition of CeO2.



中文翻译:

CeO 2对带有镍铁涂层的铁素体不锈钢互连件的氧化和电学行为的影响

铁素体不锈钢是用于固体氧化物燃料电池(SOFC)互连的有前途的材料。使用铁素体不锈钢作为互连件迫切需要解决的当前问题是它们的电阻快速增加和由氧化铬的蒸发引起的阴极中毒。在本研究中,Ni Fe和NiFe CeO 2合金涂层已电沉积到430不锈钢(430SS)上。在800°C的空气中氧化过程中,外层致密NiFe 2 O 4层和内层Cr 2 O 3保护层在涂层样品上热生长。NiFe 2 O 4层有效地阻止了铬的向外迁移。CeO 2的添加降低了Cr 2 O 3的生长速率并减少了氧化皮/合金界面附近的孔数量。此外,通过添加CeO 2已经实现了更高的电导率。

更新日期:2018-03-19
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