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Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst†
New Journal of Chemistry ( IF 3.3 ) Pub Date : 2018-03-19 00:00:00 , DOI: 10.1039/c8nj00660a
Seema Arun Ghorpade 1, 2, 3, 4, 5 , Dinesh Nanaji Sawant 1, 2, 3 , Dominik Renn 1, 2, 3 , Anna Zernickel 1, 2, 3 , Weiyuan Du 1, 2, 3 , Nagaiyan Sekar 4, 5, 6, 7, 8 , Jörg Eppinger 1, 2, 3
Affiliation  

Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol% of a Bedford-type palladacycle catalyst is described. The developed methodology is applicable for a wide range of cinnamyl acetates furnishing excellent yields of up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under an air atmosphere.

中文翻译:

使用Bedford型palladacycle催化剂将乙酸肉桂酯与四苯硼酸钠进行烯丙基芳基化的水溶液方案

描述了使用0.002mol%的贝德福德型Palladacycle催化剂,使乙酸肉桂酯与四苯基硼酸钠进行烯丙基芳基化。所开发的方法学适用于各种乙酸肉桂酯,可提供高达93%的极佳收率。值得注意的是,所有反应在空气气氛下在温和的反应条件下在水中顺利进行。
更新日期:2018-03-19
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