A Ti₄₉Zr₂₆Ni₂₅ quasicrystal alloy was prepared by mechanical alloying and subsequent annealing. Mesoporous α-Fe₂O₃ particles were obtained via a hydro-thermal procedure using chitosan as the template. Composites of Ti₄₉Zr₂₆Ni₂₅ mixed with different amounts of mesoporous α-Fe₂O₃ were synthesized to enhance the electrochemical properties of Ti₄₉Zr₂₆Ni₂₅. The structural characteristics of the alloy and composites were investigated using XRD, SEM, TEM and BET analysis. The electrochemical properties of the composite electrodes were tested using a three-electrode battery system at room temperature. The discharge capacities for the composites were higher than those for the Ti₄₉Zr₂₆Ni₂₅ alloy and reached a maximum (259.6 mAh/g) for 5% additive content of α-Fe₂O₃. Moreover, the composites showed enhanced high-rate dischargeability. The capacity decay rate and charge-transfer resistance decreased after α-Fe₂O₃ loading. The preferable performance of the composite alloys may be attributed to the doping of mesoporous α-Fe₂O₃, which may play a catalytic effect in the kinetics of the electrochemical reactions. The large surface area and mesoporous structure of α-Fe₂O₃ may also be advantageous for rapid transmission of hydrogen in the interior of the alloy, thus improving the discharge capacity of the alloy electrode.

通过机械合金化和随后的退火来制备Ti ₄₉ Zr ₂₆ Ni ₂₅准晶体合金。介孔的α-Fe ₂ ö _3个经由使用壳聚糖作为模板水热方法得到颗粒。钛的复合材料₄₉的Zr ₂₆镍₂₅与不同量的中孔的混合的α-Fe ₂ ö ₃合成，以提高钛的电化学性质₄₉的Zr ₂₆镍₂₅。使用XRD，SEM，TEM和BET分析研究了合金和复合材料的结构特征。在室温下使用三电极电池系统测试了复合电极的电化学性能。用于复合材料的放电容量比用于较高的Ti ₄₉ Zr的₂₆镍₂₅合金和达到的α-Fe的5％的添加剂含量的最大（259.6毫安/克）₂ ö ₃。此外，该复合材料显示出较高的高倍率放电性能。后的α-Fe的容量衰减率和电荷转移电阻降低₂ ö ₃加载中。复合合金的优选的性能可以归因于介孔的α-Fe的掺杂₂ Ó ₃，其可以在电化学反应的动力学中发挥催化作用。的大的表面积和的α-Fe的介孔结构₂ ö ₃也可以是用于在合金内部的氢快速传输是有利的，从而提高了合金电极的放电容量。