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Investigation on energy storage and conversion properties of multifunctional PANI-MWCNT composite
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2018-03-16 , DOI: 10.1016/j.ijhydene.2018.02.153
Atanu Roy , Apurba Ray , Samik Saha , Sachindranath Das

Polyaniline-multiwalled carbon nanotube (PANI-MWCNT) composite synthesized through chemical polymerization is investigated as a possible electrode material for supercapacitor as well as an electro-catalyst for hydrogen evolution reaction (HER) in acidic medium. UV–Vis spectroscopy, FTIR spectroscopy and field emission scanning electron microscopy (FESEM) have been used to characterize the electrode material. The binder-free electrodes were prepared and they exhibit a specific capacitance of 540.29 F g−1 at a scan rate of 2 mV s−1 in 1 M H2SO4 electrolyte. The material exhibits excellent pseudocapacitive behaviour due to the presence of PANI with long-term cyclic stability of 87.4% retention after 5000 cycles. PANI-MWCNT composite also shows good HER activity, with overpotential of −395 mV.



中文翻译:

多功能PANI-MWCNT复合材料的储能与转化性能研究。

研究了通过化学聚合反应合成的聚苯胺-多壁碳纳米管(PANI-MWCNT)复合材料,作为超级电容器的一种可能的电极材料,以及在酸性介质中用于氢释放反应(HER)的电催化剂。UV-Vis光谱,FTIR光谱和场发射扫描电子显微镜(FESEM)已用于表征电极材料。制备了无粘合剂电极,它们在1 MH 2 SO 4中的扫描速率为2 mV s -1时显示的比电容为540.29 F g -1电解质。由于PANI的存在,该材料表现出出色的伪电容性能,在5000次循环后,其长期循环稳定性为87.4%的保留率。PANI-MWCNT复合材料还显示出良好的HER活性,超电势为-395 mV。

更新日期:2018-03-16
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