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A CO2 utilization approach towards the synthesis of terephthalic acid via a catalytic double carboxylation
Journal of CO2 Utilization ( IF 7.2 ) Pub Date : 2018-03-15 , DOI: 10.1016/j.jcou.2018.01.006
Samuel J. Thompson , Thomas R. Gohndrone , Marty Lail

A catalytic double carboxylation of a bisboronate ester benzene was disclosed to synthesize terephthalic acid under a CO2 utilization approach. The double carboxylation was accomplished with several other bisboronate ester arenes to provide support for this being a general transformation. The double carboxylation was conducted on a gram scale to provide terephthalic acid in 90% yield.



中文翻译:

通过催化双羧基化合成对苯二甲酸的CO 2利用方法

公开了双硼酸酯苯的催化双羧化在CO 2利用方法下合成对苯二甲酸。用其他几种双硼酸酯酯的芳烃完成了双羧化反应,从而为一般的转化提供了支持。以克为单位进行两次羧化,以90%的产率提供对苯二甲酸。

更新日期:2018-03-15
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