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Production of syngas via glycerol dry reforming on Ni catalysts supported on mesoporous nanocrystalline Al2O3
Journal of CO2 Utilization ( IF 7.2 ) Pub Date : 2018-03-15 , DOI: 10.1016/j.jcou.2018.01.009
Masoud Tavanarad , Fereshteh Meshkani , Mehran Rezaei

Mesoporous Ni/γ- Al2O3 catalysts with various Ni contents were synthesized and employed in glycerol dry (CO2) reforming (GDR) reaction. The results revealed that increasing the Ni content from 5 to 20 wt.%, decreased the BET areas of the samples from 180 to 143 m2/g and increased the Ni crystalline size from 6.6 to 19 nm. Moreover, the catalytic activities of different catalysts were studied and the results revealed that 15 wt.% Ni/Al2O3 possessed the maximum catalytic activity. Finally, the stability of the catalyst with maximum activity was investigated for 20 h of reaction at 700 °C. The results showed a significant decline in catalytic activity during the first 5 h of reaction followed with a stable activity for 15 h time on stream.



中文翻译:

在介孔纳米晶Al 2 O 3上负载的镍催化剂上的甘油干重整制合成气

中孔镍/γ-铝2种ö 3催化剂与各种Ni含量被合成并在甘油干燥(CO采用2)重整(GDR)反应。结果表明,将Ni含量从5wt。%增加到20wt。%,将样品的BET面积从180m 3 / g减少到143m 2 / g,并且将Ni晶体尺寸从6.6nm增加到19nm。此外,研究了不同催化剂的催化活性,结果表明Ni / Al 2 O 3为15 wt%。具有最大的催化活性。最后,在700°C下反应20小时,研究了具有最大活性的催化剂的稳定性。结果显示,在反应的前5小时内,催化活性显着下降,随后在运行15小时内,其催化活性却保持稳定。

更新日期:2018-03-15
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