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NO2 sensing properties of SmFeO3 porous hollow microspheres
Sensors and Actuators B: Chemical ( IF 8.0 ) Pub Date : 2018-03-15 , DOI: 10.1016/j.snb.2018.03.073
Hao-Tian Huang , Wen-Lu Zhang , Xiao-Dong Zhang , Xin Guo

Porous hollow microspheres of SmFeO3 were prepared from a simple process involving a metal organic framework (MOF) compound as the templating precursor. With a diameter of about 2 μm, these hollow-centered microspheres are formed by nanoporous thin walls of SmFeO3. Chemoresistive gas sensors based on these microspheres exhibits excellent sensing performance on NO2 at 200 °C, including high sensitivity (response of 10.2 under 200 ppb) with detection limit as low as 50 ppb, high selectivity, and reasonably short time for response and recovery (369 s/478 s). The superior sensing response over other SmFeO3-based NO2 sensors can be ascribed to the electron-accepting reactions during NO2 adsorption, which is facilitated by the special morphological features of the microsphere.



中文翻译:

SmFeO 3多孔中空微球的NO 2传感特性

SmFeO 3多孔中空微球是通过一种简单的方法制备的,该方法涉及金属有机骨架(MOF)化合物作为模板前体。这些空心微球的直径约为2μm,由SmFeO 3的纳米多孔薄壁形成。基于这些微球的化学阻性气体传感器在200°C的条件下对NO 2表现出出色的感测性能,包括高灵敏度(200 ppb下的10.2响应),检测限低至50 ppb,高选择性以及相当短的响应和恢复时间(369 s / 478 s)。优于其他基于SmFeO 3的NO 2传感器的感应响应可归因于NO 2期间的电子接受反应 微球的特殊形态特征促进了吸附。

更新日期:2018-03-15
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