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A Novel Poly(vinylidene fluoride)-Based 4-Miktoarm Star Terpolymer: Synthesis and Self-Assembly
Molecular Pharmaceutics ( IF 4.5 ) Pub Date : 2018-03-15 00:00:00 , DOI: 10.1021/acs.molpharmaceut.8b00010 Yogesh Patil 1 , Panayiotis Bilalis 1 , George Polymeropoulos 1 , Sarah Almahdali 1 , Nikos Hadjichristidis 1 , Valentin Rodionov 1
Molecular Pharmaceutics ( IF 4.5 ) Pub Date : 2018-03-15 00:00:00 , DOI: 10.1021/acs.molpharmaceut.8b00010 Yogesh Patil 1 , Panayiotis Bilalis 1 , George Polymeropoulos 1 , Sarah Almahdali 1 , Nikos Hadjichristidis 1 , Valentin Rodionov 1
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A well-defined amphiphilic miktoarm polymer incorporating poly(vinylidene fluoride) (PVDF), polystyrene (PS), and poly(ethylene glycol) (PEG) blocks was synthesized via a combination of atom-transfer radical polymerization (ATRP), iodine transfer radical polymerization (ITP), and copper-catalyzed azide–alkyne cycloaddition (CuAAC). Morphology and self-assembly of this star polymer were examined in organic solvents and in water. The aggregates formed in water were found to possess unusual frustrated topology due to immiscibility of PS and PVDF. The polymer was evaluated for transport of small hydrophobic molecules in water.
中文翻译：
新型的基于聚偏二氟乙烯的4-Miktoarm星形三元共聚物：合成与自组装
通过原子转移自由基聚合（ATRP），碘转移自由基的组合，合成了定义明确的两亲米克聚合物，该聚合物结合了聚偏二氟乙烯（PVDF），聚苯乙烯（PS）和聚乙二醇（PEG）嵌段聚合（ITP）和铜催化的叠氮化物-炔烃环加成（CuAAC）。在有机溶剂和水中检查了这种星形聚合物的形貌和自组装。由于PS和PVDF的不混溶性，发现水中形成的聚集体具有异常的受挫拓扑。评价该聚合物在水中小的疏水分子的转运。
更新日期：2018-03-15
中文翻译：
新型的基于聚偏二氟乙烯的4-Miktoarm星形三元共聚物：合成与自组装
通过原子转移自由基聚合（ATRP），碘转移自由基的组合，合成了定义明确的两亲米克聚合物，该聚合物结合了聚偏二氟乙烯（PVDF），聚苯乙烯（PS）和聚乙二醇（PEG）嵌段聚合（ITP）和铜催化的叠氮化物-炔烃环加成（CuAAC）。在有机溶剂和水中检查了这种星形聚合物的形貌和自组装。由于PS和PVDF的不混溶性，发现水中形成的聚集体具有异常的受挫拓扑。评价该聚合物在水中小的疏水分子的转运。
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