Strain‐Promoted Cycloaddition of Cyclopropenes with o‐Quinones: A Rapid Click Reaction,Angewandte Chemie International Edition

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Strain‐Promoted Cycloaddition of Cyclopropenes with o‐Quinones: A Rapid Click Reaction
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-04-17 , DOI: 10.1002/anie.201800937
Digvijay Gahtory ₁ , Rickdeb Sen ₁ , Andriy R Kuzmyn ₁ , Jorge Escorihuela ₂ , Han Zuilhof _{1,

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Affiliation

Novel click reactions are of continued interest in fields as diverse as bio‐conjugation, polymer science and surface chemistry. Qualification as a proper “click” reaction requires stringent criteria, including fast kinetics and high conversion, to be met. Herein, we report a novel strain‐promoted cycloaddition between cyclopropenes and o‐quinones in solution and on a surface. We demonstrate the “click character” of the reaction in solution and on surfaces for both monolayer and polymer brush functionalization.

中文翻译：

环丙烯与邻醌的应变促进环加成：快速点击反应

新颖的点击反应在生物共轭、聚合物科学和表面化学等不同领域一直受到人们的关注。合格的“点击”反应需要满足严格的标准，包括快速动力学和高转化率。在此，我们报告了溶液中和表面上环丙烯和邻醌之间的新型应变促进环加成。我们展示了单层和聚合物刷功能化的溶液中和表面上反应的“点击特征”。

更新日期：2018-04-17

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