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Yb3+-doped cadmium molybdato-tungstate single crystal – its structural, optical, magnetic and transport properties
Journal of Solid State Chemistry ( IF 3.3 ) Pub Date : 2018-03-14 , DOI: 10.1016/j.jssc.2018.03.014
T. Groń , E. Tomaszewicz , M. Berkowski , M. Głowacki , M. Oboz , J. Kusz , B. Sawicki , Z. Kukuła , H. Duda

Single crystal of new cadmium and ytterbium molybdato-tungstate (Cd0.97060.0098Yb0.0196(MoO4)0.9706(WO4)0.0294, where ⎕ denotes cationic vacancies) has been successfully grown by the Czochralski method in air and under 1 MPa. X-ray crystallographic analysis reveals that the as-grown single crystal belongs to a scheelite-type structure (a = b = 5.15539(12) and c = 11.1919(3) Å, space group I41/a), in which Yb3+ ions do not show long-range order and are randomly distributed in the unit cell, substituting the Cd2+ ones. The as-grown single crystal does not show anisotropy of optical properties, i.e. its direct band gap reaches Eg = 1.76 or 1.75 eV along (100) and (001) crystallographic directions, respectively. The single crystal exhibits paramagnetic state with short-range antiferromagnetic and long-range ferrimagnetic interactions, a magnetization with zero coercivity and, a remanence that is almost a universal function of H/T, characterizing superparamagnetic-like behaviour. Electrical studies of the new ytterbium-doped cadmium molybdato-tungstate single crystal show a relatively small dielectric constant (εr < 12), large lossiness of Joule-Lenz type observed at low frequencies as well as nonlinear I-V characteristics of Schottky or Maxwell-Wagner type.



中文翻译:

掺Yb 3+的钼酸钨镉镉单晶–结构,光学,磁性和传输性质

新镉和镱molybdato-钨(CD的单晶0.97060.00980.0196(的MoO 40.9706(WO 40.0294,其中⎕表示阳离子空位)已成功地通过切克劳斯基法在空气中,并在1MPa的生长。X射线晶体学分析表明,所生长的单晶属于白钨矿型结构(a = b = 5.15539(12)和c = 11.1919(3)Å,空间群I 4 1 / a),其中Yb 3+离子不显示远距离有序,而是随机分布在晶胞中,取代了Cd 2+那些。所生长的单晶没有显示出光学特性的各向异性,即,其直接带隙分别沿(100)和(001)晶体学方向达到E g = 1.76或1.75 eV 。单晶表现出具有短程反铁磁和长程亚铁磁相互作用的顺磁态,矫顽力为零的磁化强度和剩磁几乎是H / T的通用函数,表现出超顺磁特性。对新型掺-钼酸钨-钨酸镉单晶的电学研究表明,它的介电常数相对较小(εr <12),在低频下观察到的焦耳-伦兹型损耗较大,并且非线性肖特基或麦克斯韦-瓦格纳型的IV特性。

更新日期:2018-03-15
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