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Synthesis and characterization of metal nanoparticles templated chitosan-SiO2 catalyst for the reduction of nitrophenols and dyes
Carbohydrate Polymers ( IF 10.7 ) Pub Date : 2018-03-14 , DOI: 10.1016/j.carbpol.2018.03.029
Fayaz Ali , Sher Bahadar Khan , Tahseen Kamal , Khalid A. Alamry , Esraa M. Bakhsh , Abdullah M. Asiri , Tariq R.A. Sobahi

Metal nanoparticles (MNPs) templated on chitosan-silica (CH-SiO2) nanocomposite fiber were synthesized via solution based fiber formation followed by the treatment with metal salt solution and NaBH4. The performance difference of CH-SiO2 templated with Cu, Co, Ag and Ni nanoparticles for both reduction of 4-nitroaniline (4-NA) and decolorization of Congo red (CR) was investigated. The Cu nanoparticles loaded CH-SiO2 (Cu/CH-SiO2), showed high catalytic efficiencies in the reduction of 4-NA and CR, as compared to other loaded MNPs. The apparent rate constants of 6.17 × 10−3 sec−1 and 1.68 × 10−2 sec−1 and turnover frequencies (TOF) of 4.693 hr−1 and 3.965 hr−1 were observed for the reduction of 4-NA and CR, respectively. In addition, the catalytic activity of Cu/CH-SiO2 catalyst were also examined and found efficient in the reduction of nitrophenols (2-NP, 3-NP and 4-NP), and other dyes. Thus, Cu/CH-SiO2 with excellent catalytic proficiency can also be employed for other applications.



中文翻译:

金属纳米粒子模板壳聚糖-SiO 2催化剂的合成及表征,用于还原硝基酚和染料

通过基于溶液的纤维形成,然后用金属盐溶液和NaBH 4处理,合成了以壳聚糖-二氧化硅(CH-SiO 2)纳米复合纤维为模板的金属纳米颗粒(MNP)。研究了以Cu,Co,Ag和Ni纳米粒子为模板的CH-SiO 2在4-硝基苯胺(4-NA)还原和刚果红(CR)脱色方面的性能差异。与其他负载的MNPs相比,负载有CH-SiO 2(Cu / CH-SiO 2)的铜纳米颗粒在4-NA和CR的还原中显示出高催化效率。表观速率常数为6.17×10 -3 sec -1和1.68×10 -2 sec-1和周转4.693 hr的频率(TOF)-1和3.965小时-1,观察到4-NA和CR的减少,分别。另外,还检查了Cu / CH-SiO 2催化剂的催化活性,发现其在还原硝基酚(2-NP,3-NP和4-NP)和其他染料方面有效。因此,具有优异催化能力的Cu / CH-SiO 2也可以用于其他应用。

更新日期:2018-03-14
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