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Multiple cluster CH activations and transformations of furan by triosmium carbonyl complexes†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-03-13 00:00:00 , DOI: 10.1039/c8cc01532e Richard D. Adams 1, 2, 3, 4 , Emmanuel J. Kiprotich 1, 2, 3, 4 , Mark D. Smith 1, 2, 3, 4
Chemical Communications ( IF 4.3 ) Pub Date : 2018-03-13 00:00:00 , DOI: 10.1039/c8cc01532e Richard D. Adams 1, 2, 3, 4 , Emmanuel J. Kiprotich 1, 2, 3, 4 , Mark D. Smith 1, 2, 3, 4
Affiliation
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Reaction of Os3(CO)10(NCMe)2 with the triosmium furyne complex Os3(CO)9(μ3,η2-C4H2O)(μ-H)2, 1 yielded the bis-triosmium complex 2 containing a bridging furyenyl ligand by CH activation at the uncoordinated C–C double bond. Heating 2 led to additional CH activation with formation of the first furdiyne C4O ligand in the complex Os3(CO)9(μ-H)2(μ3-η2-2,3-μ3-η2-4,5-C4O)Os3(CO)9(μ-H)2, 3. The furdiyne ligand in 3 was subsequently ring-opened and decarbonylated to yield products 4 and 5 containing novel bridging C3 ligands. Complex 2 also undergoes ring opening to yield an intermediate Os3(CO)9(μ-H)(μ3-η2-μ-η2-CH–C–CH–C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
O)Os3(CO)10(μ-H), 6 which was also decarbonylated thermally to yield 4 and 5. All products were characterized by a combination of IR, NMR, mass spec and single-crystal X-ray diffraction analyses.
中文翻译：
羰基tri配合物对CH的多簇CH活化和呋喃的转化†
O的反应3（CO）10（NCMe）2与triosmium furyne复杂锇3（CO）9（μ 3，η 2 -C 4 ħ 2 O）（μ-H）2，1得到的双- triosmium复杂2在非配位的CC双键处通过CH活化含有桥联的呋喃基配体。加热2导致额外CH激活与在形成第一furdiyne的C 4中的O复杂锇配位体3（CO）9（μ-H）2（μ 3 -η 2-2,3-μ 3 -η 2 -4,5--C 4 O）O的3（CO）9（μ-H）2，3。随后将3中的呋喃炔配体开环并脱羰基，得到含有新颖桥连C 3配体的产物4和5。复杂2也经历开环，得到中间体O的3（CO）9（μ-H）（μ 3 -η 2 -μ-η 2 -CH-C-CH-C O）O的3（CO）10（μ -H），6其也被热脱羰，得到4和5。所有产品均通过IR，NMR，质谱和单晶X射线衍射分析进行了表征。
更新日期：2018-03-13
O)Os3(CO)10(μ-H), 6 which was also decarbonylated thermally to yield 4 and 5. All products were characterized by a combination of IR, NMR, mass spec and single-crystal X-ray diffraction analyses.
中文翻译：
羰基tri配合物对CH的多簇CH活化和呋喃的转化†
O的反应3（CO）10（NCMe）2与triosmium furyne复杂锇3（CO）9（μ 3，η 2 -C 4 ħ 2 O）（μ-H）2，1得到的双- triosmium复杂2在非配位的CC双键处通过CH活化含有桥联的呋喃基配体。加热2导致额外CH激活与在形成第一furdiyne的C 4中的O复杂锇配位体3（CO）9（μ-H）2（μ 3 -η 2-2,3-μ 3 -η 2 -4,5--C 4 O）O的3（CO）9（μ-H）2，3。随后将3中的呋喃炔配体开环并脱羰基，得到含有新颖桥连C 3配体的产物4和5。复杂2也经历开环，得到中间体O的3（CO）9（μ-H）（μ 3 -η 2 -μ-η 2 -CH-C-CH-C O）O的3（CO）10（μ -H），6
其也被热脱羰，得到4和5。所有产品均通过IR，NMR，质谱和单晶X射线衍射分析进行了表征。
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