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Bis(amino)cyclopropenylidene Catalyzed Rauhut–Currier Reaction between α,β-Unsaturated Carbonyl Compounds and para-Quinone Methides
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2018-03-13 00:00:00 , DOI: 10.1021/acs.joc.8b00225
Prithwish Goswami 1 , Sonam Sharma 1 , Gurdeep Singh 1 , Ramasamy Vijaya Anand 1
Affiliation  

An intermolecular Rauhut–Currier reaction between α,β-unsaturated carbonyl compounds and p-quinone methides has been developed by employing bis(amino)cyclopropenylidene as a catalyst. This protocol allows access to a variety of vinyl diarylmethane derivatives in moderate to good yields.

中文翻译:

双(氨基)环丙烯基催化α,β-不饱和羰基化合物与对-醌醌间的Rauhut-Currier反应

通过使用双(氨基)环丙烯基作为催化剂,开发了α,β-不饱和羰基化合物与苯二甲酰甲基之间的分子间Rauhut-Currier反应。该方案允许以中等至良好的产率获得各种乙烯基二芳基甲烷衍生物。
更新日期:2018-03-13
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