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Ni(II)/Zn(II)-Triazolate Clusters Based MOFs Constructed from a V-Shaped Dicarboxylate Ligand: Magnetic Properties and Phosphate Sensing
Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2018-03-12 , DOI: 10.1016/j.jssc.2018.03.015
Yong-Qiang Chen , Yuan Tian , Na Li , Sui-Jun Liu

Two isomorphous metal-organic frameworks (MOFs) {[M2(μ3-OH)(trz)(sdba)(H2O)]·3H2O} (M = Ni for 1, Zn for 2, Htrz = 1,2,4-triazole, H2sdba = 4,4ʹ-sulfonyldibenzoate) were obtained under the same reaction condition. Both of complexes present a three dimensional 8-c framework with whc1 topology based on M4-(μ3-OH) units. Moreover, the magnetic properties of 1 and anion sensing of 2 were investigated. The magnetic study show that the domain antiferromagnetic interactions exist in 1. However, complex 2 can be considered as a promising chemical sensor for detecting PO4by means of fluorescence enhancement among various anions in aqueous solutions.



中文翻译:

基于V型二羧酸配体构建的Ni(II)/ Zn(II)-三重氮盐簇的MOF:磁性和磷酸盐感测

两个同晶金属-有机骨架(MOF){[M 2μ 3 -OH)(TRZ)(sdba)(H 2 O)]·3H 2 ö} (M =镍为1,锌为2,Htrz =在相同反应条件下获得1,2,4-三唑,H 2 sdba = 4,4′-磺酰基苯甲酸酯。两个配合物呈现三维8- Ç框架与whc1基于M拓扑4 - (μ 3 -OH)单元。此外,磁特性为1,阴离子感测为2被调查了。磁性研究表明,畴反铁磁相互作用存在于1中。然而,络合物2可以被认为是通过在水溶液中各种阴离子之间增强荧光来检测PO 4 3 的有前途的化学传感器。

更新日期:2018-03-13
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