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Selective production of aromatic hydrocarbons from lignocellulosic biomass via catalytic fast-hydropyrolysis using W2C/γ-Al2O3
Catalysis Communications ( IF 3.4 ) Pub Date : 2018-03-11 , DOI: 10.1016/j.catcom.2018.03.011
Kavimonica Venkatesan , Songbo He , Kulathu Seshan , Parasuraman Selvam , Ravikrishnan Vinu

This study is focused on fast hydropyrolysis of biomass followed by upgradation of pyrolysates over γ-alumina-supported tungsten carbide catalyst (W2C/γ-Al2O3). The catalyst was prepared by wet-impregnation followed by carburization, and was characterized by various techniques. Catalytic fast-hydropyrolysis experiments were performed at 500 °C in an analytical pyrolyzer coupled with gas chromatograph-mass spectrometer using pine-wood, cellulose and lignin as the feedstocks. W2C/γ-Al2O3 is proved to be an efficient hydrodeoxygenation catalyst producing aromatic and aliphatic hydrocarbons at 82% and 15% selectivities, respectively. Further, the activity of W2C/γ-Al2O3 catalyst is better than γ-Al2O3 and WO3/γ-Al2O3 in terms of both hydrocarbon selectivity and biomass conversion.



中文翻译:

选择性地生产从木质纤维素生物质芳香族烃的通过催化快速加氢利用了W 2 C /γ-Al系2 ö 3

这项研究的重点是生物质的快速加氢然后用γ-氧化铝负载的碳化钨催化剂热解的升级换代(W 2 C /γ-Al系2 ö 3)。通过湿浸渍然后渗碳来制备催化剂,并通过各种技术对其进行表征。催化快速加氢热解实验是在分析型热解仪和气相色谱-质谱联用的500℃下进行的,其中使用松木,纤维素和木质素作为原料。w ^ 2 C /γ-Al系2 ö 3被证明是产生在82%的芳族和脂族烃和15层%的选择性的有效加氢脱氧催化剂,分别。此外,W 2的活性C /γ-Al系2 ö 3催化剂比的γ-Al更好2 ö 3和WO 3 /γ-Al系2 ö 3在这两个烃的选择性和生物质转化的条款。

更新日期:2018-03-11
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