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Amberene and 1-methylamberene, isolated and identified from Kuji amber (Japan)
Organic Geochemistry ( IF 2.6 ) Pub Date : 2018-06-01 , DOI: 10.1016/j.orggeochem.2018.02.014
Tetsuaki Kawamura , Hiroyuki Koshino , Takemichi Nakamura , Yoshiyuki Nagasawa , Hidetaka Nanao , Masayuki Shirai , Shota Uesugi , Misa Ohno , Ken-ichi Kimura

Abstract Abundant labdatriene derivatives, named amberene [15,19,20-trinor-5,7,9-labdatriene (or 1,6-dimethyl-5-isopentyltetralin) (1)] and 1-methylamberene [15,20-dinor-5,7,9-labdatriene (or 1,1,6-trimethyl-5-isopentyltetralin) (2)] were isolated from the methanol extract of Kuji amber by HPLC. The structures were elucidated by spectral analyses including EIMS, 1D and 2D NMR and some previous assignments corrected.

中文翻译:

Amberene 和 1-methylamberene,从 Kuji amber(日本)中分离和鉴定

摘要 丰富的labdatriene衍生物,命名为amberene [15,19,20-trinor-5,7,9-labdatriene (or 1,6-dimethyl-5-isopentyltetralin) (1)] 和 1-methylamberene [15,20-dinor- 5,7,9-labdatriene (或 1,1,6-trimethyl-5-isopentyltetralin) (2)] 用高效液相色谱法从久慈琥珀的甲醇提取物中分离出来。通过包括 EIMS、1D 和 2D NMR 在内的光谱分析阐明了结构,并修正了一些先前的分配。
更新日期:2018-06-01
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