Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes†,Chemical Communications

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Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-03-09 00:00:00 , DOI: 10.1039/c8cc01529e
Sam Yruegas _{1,

2,

3,

4} , Jesse J. Martinez _{1,

2,

3,

4} , Caleb D. Martin _{1,

2,

3,

4}

Affiliation

The reactions of 9-borafluorenes with organic azides result in either the insertion of the α-nitrogen and elimination of N₂ or the insertion of the γ-nitrogen to generate the corresponding phenanthrene analogues with boron and nitrogen in the 9- and 10-positions, respectively.

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