An Alumino‐Mannich Reaction of Organoaluminum Reagents, Silylated Amines, and Aldehydes,Chemistry - A European Journal

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An Alumino‐Mannich Reaction of Organoaluminum Reagents, Silylated Amines, and Aldehydes
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-03-26 , DOI: 10.1002/chem.201801012
Anika Tarasewicz ₁ , Deeba Ensan ₁ , Robert A. Batey ₁

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A multi‐component coupling using organoaluminum reagents, silylated amines, and aldehydes results in the formation of tertiary amines. Both alkenyl‐ and alkylaluminum reagents undergo reaction with iminium ion substrates for which the corresponding Petasis borono‐Mannich reactions are unsuccessful.

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