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Divergent Strategy in Natural Product Total Synthesis
Chemical Reviews ( IF 51.4 ) Pub Date : 2018-03-08 00:00:00 , DOI: 10.1021/acs.chemrev.7b00653
Lei Li 1 , Zhuang Chen 1 , Xiwu Zhang 1 , Yanxing Jia 1
Affiliation  

The divergent total syntheses of complex natural products from a common intermediate have attracted enormous attention in the chemical community in the past few years because it can improve the efficiency of chemical synthesis. A number of powerful and unified strategies have been developed by emulating the natural biosynthesis or through innovative transformations. This review focuses on the total synthesis of natural products by applying divergent strategies and the literature covering from 2013 to June 2017. On the basis of where the diversity comes from, the examples are grouped into three parts and discussed in detail. In each group, the examples that synthesize natural products belonging to the same subfamily are put together to contrast with one another.

中文翻译:

天然产物全合成的发散策略

在过去的几年中,来自一种常见中间体的复杂天然产物的不同总合成方法在化学界引起了极大的关注,因为它可以提高化学合成的效率。通过模拟自然的生物合成或通过创新的改造,已经开发出许多强大而统一的策略。这篇综述着重于通过运用不同的策略和涵盖2013年至2017年6月的文献对天然产物的总合成。基于多样性的来源,将这些实例分为三个部分并进行了详细讨论。在每一组中,将合成属于同一亚家族的天然产物的实例放在一起进行对比。
更新日期:2018-03-08
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