Waste HD-PE plastic, deformation into liquid hydrocarbon fuel using pyrolysis-catalytic cracking with a CuCO3 catalyst†,Sustainable Energy & Fuels

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Waste HD-PE plastic, deformation into liquid hydrocarbon fuel using pyrolysis-catalytic cracking with a CuCO3 catalyst†
Sustainable Energy & Fuels ( IF 5.0 ) Pub Date : 2018-03-08 00:00:00 , DOI: 10.1039/c8se00040a
Man Vir Singh _{1,

2,

3} , Sudesh Kumar _{1,

2,

3} , Moinuddin Sarker _{4,

5,

6,

7}

Affiliation

Waste high-density poly(ethylene) (HD-PE) plastic deformation into liquid hydrocarbon fuel using a pyrolysis-catalytic cracking process with a copper carbonate (CuCO₃) catalyst, at a temperature range from 23 °C to 390 °C. The pyrolysis-catalytic deformation process will help in environmental purification. The liquid hydrocarbons collected for use as a fuel were analyzed using Fourier-transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), two-dimensional gas chromatography/time of flight mass spectrometry (2D-GCxGC/TOFMS), inductively coupled plasma (ICP) analysis, and carbon, hydrogen, nitrogen, sulfur, and oxygen (CHNS/O) elemental analysis. The 2D-GCxGC/TOFMS results showed that various types of hydrocarbon compounds (aliphatics, aromatics, cyclics olefins, and phenanthrene) were available in the liquid hydrocarbon fuel. The conversion rates in four experiments which converted waste HD-PE plastic into liquid hydrocarbons for use as fuel were 85%, 90%, 94%, 92%, light gases 14.67%, 9.66%, 5.64%, 7.45% and residues 0.33%, 034%, 0.36%, 0.55%. Liquid hydrocarbons as fuel were found to be appropriate for use in petrol and diesel engines and they were found to be a good source of organic compounds/petrochemicals.

中文翻译：

废HD-PE塑料，通过使用CuCO ₃催化剂进行热解催化裂化而转变为液态烃燃料†

使用碳酸铜（CuCO ₃）催化剂，温度范围为23°C至390°C。热解-催化变形过程将有助于环境净化。使用傅立叶变换红外光谱（FT-IR），核磁共振（NMR），热重分析（TGA），二维气相色谱/飞行时间质谱（2D- GCxGC / TOFMS），电感耦合等离子体（ICP）分析以及碳，氢，氮，硫和氧（CHNS / O）元素分析。2D-GCxGC / TOFMS结果表明，液态烃燃料中可使用各种类型的烃化合物（脂族，芳烃，环烯烃和菲）。在将废HD-PE塑料转化为液态烃用作燃料的四个实验中，转化率分别为85％，90％，94％，92％，轻气体14.67％，9.66％，5.64％，7.45％和残留物0.33％，034％，0.36％，0.55％。发现液态烃作为燃料适合用于汽油和柴油发动机，并且发现它们是有机化合物/石化产品的良好来源。

更新日期：2018-03-08

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