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Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions
CrystEngComm ( IF 3.1 ) Pub Date : 2018-03-07 00:00:00 , DOI: 10.1039/c8ce00023a
Bo-Wen Hu 1, 2, 3, 4, 5 , Sylvie Ferlay 1, 2, 3, 4, 5 , Nathalie Gruber-Kyritsakas 1, 2, 3, 4, 5 , Mir Wais Hosseini 1, 2, 3, 4, 5
Affiliation  

Solid solutions of hydrogen bonded networks of the formula ((1-2H+)3x(2-2H+)3(1–x)([Fe(CN)6]23−))·nH2O, where (1-2H+) and (2-2H+) are bisamidinium H bond donor entities, have been prepared and structurally analysed. The H bonded systems display a honeycomb-like structure, and depending on the x value, three different tilings of the (6,3) system are observed, leading to three different phases. The precise location of the H bond donor cations (2-2H+) has been determined, evidencing H bonding between adjacent cations. The thermal properties of the solid solutions have been studied.

中文翻译:

结构相图和异构性不易弯曲的蜂窝状二维氢键固溶体

式((1 -2H +3 x2 -2H +3(1– x([Fe(CN)6 ] 2 3−))· n H 2 O的氢键网络的固溶体,其中(1 -2H +)和(2 -2H +)是双ami鎓H键供体,已经制备并进行了结构分析。H键合系统显示出蜂窝状结构,并且取决于x值(6,3)的三个不同的平铺被观察到,导致三个不同的阶段。已确定H键供体阳离子(2 -2H +)的精确位置,证明相邻阳离子之间存在H键。已经研究了固溶体的热性质。
更新日期:2018-03-07
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