Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation†,Chemical Communications

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Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-03-07 00:00:00 , DOI: 10.1039/c8cc00453f
N. A. Race _{1,

2,

3} , W. Zhang _{1,

2,

3} , M. E. Screen _{1,

2,

3} , B. A. Barden _{1,

2,

3} , W. R. McNamara _{1,

2,

3}

Affiliation

A series of Fe(III) complexes was recently reported that are active for photocatalytic hydrogen generation when paired with fluorescein and triethylamine. Herein we report an Fe(III) complex immobilized on TiO₂ and SrTiO₃ that is significantly more active than the homogeneous system, achieving up to 7800 turnovers in 31 hours.

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