Copper-catalyzed decarboxylative cyclization via tandem C–P and C–N bond formation: access to 2-phosphorylmethyl indoles†,Chemical Communications

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Copper-catalyzed decarboxylative cyclization via tandem C–P and C–N bond formation: access to 2-phosphorylmethyl indoles†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-03-07 00:00:00 , DOI: 10.1039/c8cc00739j
Bao-Cheng Wang _{1,

2,

3,

4,

5} , Ya-Ni Wang _{1,

2,

3,

4,

5} , Mao-Mao Zhang _{1,

2,

3,

4,

5} , Wen-Jing Xiao _{1,

2,

3,

4,

5} , Liang-Qiu Lu _{1,

2,

3,

4,

5}

Affiliation

A novel copper-catalyzed decarboxylative cyclization of ethynyl benzoxazinanones with P(O)H compounds has been developed. This protocol leads to a series of 2-phosphorylmethyl indoles with high efficiency and selectivity (up to 99% yield) through tandem C–P/C–N bond formation under mild conditions.

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