Electrochemical C−O Bond Formation: Facile Access to Aromatic Lactones,Chemistry - A European Journal

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Electrochemical C−O Bond Formation: Facile Access to Aromatic Lactones
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-04-20 , DOI: 10.1002/chem.201801108
Xiang-Zhang Tao ₁ , Jian-Jun Dai ₁ , Jie Zhou ₁ , Jun Xu ₁ , Hua-Jian Xu ₁

Affiliation

An efficient and robust methodology based on electrochemical techniques for the direct synthesis of aromatic lactones through dehydrogenative C−O cyclization is described. This new and useful electrochemical reaction can tolerate a variety of functional groups, and is scalable to 100 g under mild conditions. Remarkably, heterocycle‐containing substrates can be employed, thus expanding the scope of radical C−O cyclization reactions.

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