A novel superhydrophobic ternary graphene/amorphous carbon/nickel (G-Ni/a-C:H) carbon-based film was fabricated by a green approach of high-voltage electrochemical deposition without using aqueous solution, which was systematically investigated including the structure and relating applications on self-cleaning and corrosion resistance. Graphene and nickel nano-particle inserts were effective to tailor the feature of nanocrystallite/amorphous microstructure as well as micro-nanoscale hierarchical rose-petal-like surface for G-Ni/a-C:H carbon-based film. Surprisingly, this deposit could present outstanding superhydrophobicity with the contact angle of 158.98 deg and sliding angle of 2.75 deg without any further surface modification meanwhile it could possess fairly well adhesion. Furthermore, the superhydrophobic G-Ni/a-C:H carbon-based film could exhibit excellent corrosion resistance and self-cleaning performances compared to no graphene incorporated deposit. The procedure of fabricating deposit might be simple, scalable, and environmental friendly, indicating a promising prospect for industrial applications in the field of anti-fouling, anti-corrosion and drag resistance.

通过绿色高压电化学沉积法在不使用水溶液的情况下，制备了新型超疏水三元石墨烯/非晶碳/镍（G-Ni / aC：H）碳基薄膜，并对其结构和相关应用进行了系统的研究。具有自洁性和耐腐蚀性。石墨烯和镍纳米粒子插入物可有效地为G-Ni / aC：H碳基薄膜定制纳米微晶/非晶微结构以及微纳级分层玫瑰花瓣状表面的特征。出人意料的是，该沉积物可以表现出优异的超疏水性，其接触角为158.98度，滑动角为2.75度，而没有任何进一步的表面改性，同时它具有相当好的附着力。此外，超疏水性G-Ni / aC：与未掺入石墨烯的沉积物相比，H碳基薄膜可表现出优异的耐腐蚀性和自清洁性能。沉积物的制备过程可能简单，可扩展且对环境友好，这表明在防污，防腐蚀和抗阻力领域的工业应用前景广阔。