Visible‐Light‐Driven Carbon Dioxide Reduction Coupled with Water Oxidation by a Composite Soft‐Oxometalate (SOM) System,ChemistrySelect

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Visible‐Light‐Driven Carbon Dioxide Reduction Coupled with Water Oxidation by a Composite Soft‐Oxometalate (SOM) System
ChemistrySelect ( IF 1.9 ) Pub Date : 2018-03-06 , DOI: 10.1002/slct.201703093
Subharanjan Biswas _{1,

2} , Ramudu Pochamoni _{1,

2} , Soumyajit Roy _{1,

2}

Affiliation

Nature's energy needs are met by systems of renewable resources. Light is used to activate reduction of CO₂ while water is oxidized producing energy storage molecules like carbohydrates. Emulating such systems is a challenge. Here we report a visible light driven hybrid soft‐oxometalate based catalyst system that couples CO₂ reduction with water oxidation with the highest turnover number of over 1780 per mole and turnover frequency of 534 h⁻¹ of catalyst.

中文翻译：

复合软氧化金属（SOM）系统将可见光驱动的二氧化碳还原与水氧化相结合

可再生资源系统可以满足自然界的能源需求。当水被氧化时，光被用来激活CO _2的还原，从而产生诸如碳水化合物的储能分子。模拟这样的系统是一个挑战。在这里，我们报告了一种基于可见光驱动的基于混合软金属氧化物的催化剂体系，该体系将CO ₂还原与水氧化结合在一起，其最高周转数超过每摩尔1780 ，催化剂的周转频率为534 h ^-1。

更新日期：2018-03-06

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