Iron‐Catalyzed Synthesis of Amines and Thioethers Directly from Allylic Alcohols,Asian Journal of Organic Chemistry

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Iron‐Catalyzed Synthesis of Amines and Thioethers Directly from Allylic Alcohols
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-03-23 , DOI: 10.1002/ajoc.201800083
Dan‐Yang Wang ₁ , Xiao‐Min Peng ₁ , Guang‐Zhu Wang ₁ , Ya‐Juan Zhang ₁ , Tao Guo ₂ , Pan‐Ke Zhang ₁

Affiliation

A straightforward and efficient approach for the synthesis of allylic amines and thioethers has been developed by an iron‐catalyzed cross‐coupling reaction using diphosphite ligand. The reaction between allylic alcohols and amines/thiols gave allylic amine and thioester. The method is compatible with various functional groups, affording products with high yield and monoallylation selectivity.

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