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Light‐Responsive Shape: From Micrometer‐Long Nanocylinders to Compact Particles in Electrostatic Self‐Assembly
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2018-03-05 , DOI: 10.1002/marc.201700860
Giacomo Mariani 1, 2 , Anja Krieger 1 , Daniel Moldenhauer 1 , Ralf Schweins 2 , Franziska Gröhn 1
Affiliation  

A light‐triggered shape change of supramolecular nanostructures is achieved through electrostatically self‐assembly of linear polyelectrolytes and oppositely charged dyes in aqueous solution: Upon UV‐irradiation, 1‐µm‐long, flexible cylinders with a cross‐section of 10 nm convert into ellipsoids of 400 nm × 40 nm. The nano‐object shape is encoded in the molecular dye structure.

中文翻译:

光响应形状:从微米级长纳米圆柱体到静电自组装中的紧密颗粒

线性聚电解质和带相反电荷的染料在水溶液中的静电自组装,可触发超分子纳米结构的形状变化:在紫外线照射下,横截面为10 nm的1 µm长的柔性圆柱体将转换为椭圆形为400 nm×40 nm。纳米物体的形状编码在分子染料结构中。
更新日期:2018-03-05
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