Silver ethynide clusters constructed with fluorinated β-diketonate ligands†,CrystEngComm

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Silver ethynide clusters constructed with fluorinated β-diketonate ligands†
CrystEngComm ( IF 2.6 ) Pub Date : 2018-03-05 00:00:00 , DOI: 10.1039/c8ce00243f
Jun-Ling Jin _{1,

2,

3,

4,

5} , Yang-Lin Shen _{1,

2,

3,

4,

5} , Yun-Peng Xie _{1,

2,

3,

4,

5} , Xing Lu _{1,

2,

3,

4,

5}

Affiliation

A fluorinated β-diketonate hexafluoroacetylacetone ligand has been employed to construct eight new silver ethynide clusters. Single crystal X-ray analysis revealed that complexes 1–8 are functionalized by hexafluoroacetylacetones as terminal ligands. In compounds 3–8, different kinds of silver ethynide cluster shells enclose various templates, respectively. In 7 and 8, the tert-butylphosphonate ligand functions as a tripodal strut to support the vertex-sharing or fusion of two small silver(I) clusters to form an enlarged composite cluster.

中文翻译：

用氟化的β-二酮酸酯配体构建的乙炔银簇†

氟化的β-二酮酸酯六氟乙酰丙酮配体已被用于构建八个新的乙炔银簇。单晶X射线分析表明，配合物1-8被六氟乙酰丙酮官能化为末端配体。在化合物3–8中，不同种类的乙炔银簇壳分别包含各种模板。在7和8中，膦酸叔丁酯配体起三脚架支撑的作用，以支持两个小银（I）簇的顶点共享或融合，从而形成扩大的复合簇。

更新日期：2018-03-05

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