Composites Part A: Applied Science and Manufacturing ( IF 8.7 ) Pub Date : 2018-03-05 , DOI: 10.1016/j.compositesa.2018.03.003 Shafagh D. Tohidi , Ana Maria Rocha , Nadya V. Dencheva , Zlatan Denchev
Knitted reinforced single polymer laminate composites based on polyamide 6 () were produced by compression molding of polyamide 6 microparticles powder-coating annealed PA6 Rib or Jersey knitted textile structures. The were synthesized by solution/precipitation activated anionic ring-opening polymerization of ε-caprolactam. The tensile properties of were studied in relation to the knitted reinforcement architecture, fiber volume fraction, ply orientation and stacking orders. The tensile stiffness and strength of the newly prepared with fiber content of 15% showed significant improvements as compared to the neat anionic PA6 matrix and to commercial hydrolytic PA6 (HPA6). The mechanical behavior of the was correlated with the geometry parameters of the knitted reinforcements, the polymorph content of the samples and their crystallinity indexes determined by differential scanning calorimetry and wide-angle X-ray diffraction. The fracture behavior of was investigated by electron microscopy complemented by simulation studies.
中文翻译:
针织物和聚酰胺微粒压缩成型的单聚合物层压复合材料:制备与结构-性能关系
基于聚酰胺6的针织增强型单聚合物层压复合材料)是通过聚酰胺6微粒的压缩成型生产的 粉末涂层退火的PA6罗纹或泽西针织织物结构。这通过溶液/沉淀活化的ε-己内酰胺阴离子开环聚合反应合成。的拉伸性能对针织增强结构,纤维体积分数,帘布层取向和堆叠顺序进行了研究。新制备的拉伸刚度和强度与纯阴离子PA6基质和市售水解PA6(HPA6)相比,纤维含量为15%的纤维具有明显的改善。机械性能通过差示扫描量热法和广角X射线衍射确定针织增强物的几何参数,样品的多晶型物含量及其结晶度指数。的断裂行为 通过电子显微镜进行了研究,并辅以模拟研究。