Ruthenium-catalyzed hydrogen isotope exchange of C(sp3)–H bonds directed by a sulfur atom,Chemical Communications

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Ruthenium-catalyzed hydrogen isotope exchange of C(sp3)–H bonds directed by a sulfur atom
Chemical Communications ( IF 4.3 ) Pub Date : 2018-03-05 00:00:00 , DOI: 10.1039/c8cc00653a
Longhui Gao _{1,

2,

3} , Serge Perato _{1,

2,

3} , Sébastien Garcia-Argote _{1,

2,

3} , Céline Taglang _{1,

2,

3} , Luis Miguel Martínez-Prieto _{4,

5,

6,

7,

8} , Céline Chollet _{1,

2,

3} , David-Alexandre Buisson _{1,

2,

3} , Vincent Dauvois _{3,

9,

10,

11} , Philippe Lesot _{12,

13,

14,

15,

16} , Bruno Chaudret _{4,

5,

6,

7,

8} , Bernard Rousseau _{1,

2,

3} , Sophie Feuillastre _{1,

2,

3} , Grégory Pieters _{1,

2,

3}

Affiliation

SCBM, CEA, Université Paris Saclay
Gif-sur-Yvette
France
LPCNO
Laboratoire de Physique et Chimie de Nano-Objets
UMR 5215 INSA-CNRS-UPS
Institut National des Sciences Appliquées
31077 Toulouse
CEA Saclay
DEN/DANS/DPC/SECR/LRMO
91191 Gif sur Yvette
RMN en Milieu Orienté
ICMMO
UMR CNRS 8182
Université Paris-Sud/Université Paris-Saclay
91405 Orsay cedex

We present here the first example of C(sp³)–H activation directed by a sulfur atom. Based on this transformation catalyzed by Ru/C, we have developed a hydrogen isotope exchange reaction for the deuterium and tritium labelling of thioether substructures in complex molecules.

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