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Green synthesis of fluorescent carbon quantum dots for the detection of mercury(ii) and glutathione†
New Journal of Chemistry ( IF 3.3 ) Pub Date : 2018-03-02 00:00:00 , DOI: 10.1039/c8nj00432c
Daraksha Bano 1, 2, 3, 4, 5 , Vijay Kumar 1, 2, 3, 4, 5 , Vikas Kumar Singh 1, 2, 3, 4, 5 , Syed Hadi Hasan 1, 2, 3, 4, 5
Affiliation  

Herein, we report a green synthetic approach for the synthesis of water-soluble fluorescent CQDs via a simple one-step hydrothermal treatment using Tamarindus indica leaves for the first time. The prepared CQDs show an excitation-dependent behavior in the range from 260 to 400 nm with a high QY of approximately 46.6%. Further, the prepared CQDs serve as a very sensitive nanoprobe for the turn-off sensing of Hg2+ with a minimum LOD as low as 6 nM in the dynamic range from 0 to 0.1 μM. The attractiveness of the present sensing system is that it further acts as a turn-on sensor for GSH detection with good selectivity. The feasibility of the present sensing system is also examined using pond water samples for the detection of Hg2+. Thus, the present sensing system is reliable for sensing and several another analytical applications.

中文翻译:

荧光碳量子点的绿色合成,用于检测汞(ii)和谷胱甘肽

在这里,我们首次报道了一种绿色合成方法,该方法首次通过简单的一步式水热处理使用罗望子(Tamarindus indica)叶来合成水溶性荧光CQD 。制备的CQD在260至400 nm范围内表现出与激发有关的行为,其高QY约为46.6%。此外,制备的CQD用作非常灵敏的纳米探针,用于在0至0.1μM的动态范围内关断检测Hg 2+,最小LOD低至6 nM。本传感系统的吸引力在于,它还具有良好的选择性,进一步用作GSH检测的开启传感器。还使用池塘水样本检测Hg 2+来检查本传感系统的可行性。。因此,本感测系统对于感测和其他几种分析应用是可靠的。
更新日期:2018-03-02
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