Stepwise syntheses and supramolecular assemblies of a series of polyoxovanadate hybrids with various architectures†,New Journal of Chemistry

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Stepwise syntheses and supramolecular assemblies of a series of polyoxovanadate hybrids with various architectures†
New Journal of Chemistry ( IF 2.7 ) Pub Date : 2018-03-02 00:00:00 , DOI: 10.1039/c7nj04727d
Bo Huang _{1,

2,

3,

4,

5} , Nan Wang _{1,

2,

3,

4,

5} , Kang Yang _{1,

2,

3,

4,

5} , Degang Ke _{1,

2,

3,

4,

5} , Yajun Fang _{1,

2,

3,

4,

5} , Xunliang Hu _{1,

2,

3,

4,

5} , Baolin Wu _{1,

2,

3,

4,

5} , Zicheng Xiao _{1,

2,

3,

4,

5} , Pingfan Wu _{1,

2,

3,

4,

5} , Yongge Wei _{1,

2,

3,

4,

5}

Affiliation

By controlling the terminal organic ligands, various fascinating supramolecular assemblies originating from hydrogen bonding interactions in different dimensions in a series of hexavanadate hybrids were synthesized via step-by-step organic modification. These hybrids were characterized, and their structures were determined by single-crystal X-ray diffraction. Moreover, the introduction of a rigid bridging ligand has a positive influence on the assembly of supramolecular architectures, providing a new vision for the design and synthesis of advanced inorganic–organic materials.

中文翻译：

一系列具有不同结构的聚氧钒酸盐杂化体的逐步合成和超分子组装†

通过控制末端有机配体，通过逐步的有机修饰，合成了一系列迷人的超分子组装体，这些组装体源自一系列六钒酸盐杂化物中不同尺寸的氢键相互作用。对这些杂化物进行了表征，并通过单晶X射线衍射确定了它们的结构。此外，刚性桥接配体的引入对超分子结构的组装具有积极影响，为高级无机-有机材料的设计和合成提供了新的视野。

更新日期：2018-03-02

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