Temperature-dependent self-assembly of a purely organic cage in water†,Chemical Communications

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Temperature-dependent self-assembly of a purely organic cage in water†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-03-02 00:00:00 , DOI: 10.1039/c8cc01085d
Xujun Zheng _{1,

1,

2,

3,

4} , Yang Zhang _{1,

2,

3,

4} , Guangcheng Wu _{1,

2,

3,

4} , Ji-Ren Liu _{1,

2,

3,

4} , Ning Cao _{1,

2,

3,

4} , Lei Wang _{1,

5,

6,

7} , Yan Wang _{1,

2,

3,

4} , Xiaopeng Li _{1,

5,

6,

7} , Xin Hong _{1,

2,

3,

4} , Chuluo Yang _{1,

8,

9,

10,

11} , Hao Li _{1,

2,

3,

4}

Affiliation

Using a novel dynamic covalent approach relying on reversible hydrazone formation, a purely organic 3-dimensional prismatic cage was developed in water at elevated temperatures. By lowering the temperature, the hydrazone bond becomes kinetically inert. This self-assembled cage acts as an effective receptor for donor–acceptor pairs, whose interactions are weak in the absence of the cage.

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