Eco‐Friendly Selenoamidation of Alkenes with Sulfamides and Organoseleniums: Rapid access to β‐Amidoselenides,Asian Journal of Organic Chemistry

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Eco‐Friendly Selenoamidation of Alkenes with Sulfamides and Organoseleniums: Rapid access to β‐Amidoselenides
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2018-03-02 , DOI: 10.1002/ajoc.201800030
Yingjie Liu ₁ , Changhao Li ₂ , Shiqiang Mu ₂ , Yali Li ₂ , Ranran Feng ₂ , Kai Sun ₂

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An eco‐friendly method has been developed for the 1,2‐selenoamidation of alkenes under metal‐free conditions. The reaction avoids the need for pre‐prepared Se−N regents, providing facile access to a variety of β‐amidoselenides with good regioselectivity and functional group tolerance. The broad substrate scope, good regioselectivity and easy derivation make this reaction attractive for the synthesis of nitrogen‐ and selenium‐containing molecules.

中文翻译：

用硫酰胺和有机硒对烯烃进行环保的硒酰胺化：快速获得β-酰胺基硒化物

已开发出一种在无金属条件下对烯烃进行1,2-硒酰胺化的环保方法。该反应避免了对预先制备的Se-N试剂的需求，从而可以轻松获得具有良好的区域选择性和官能团耐受性的各种β-ami酰胺。广泛的底物范围，良好的区域选择性和易于衍生的特性使该反应对于合成含氮和硒的分子具有吸引力。

更新日期：2018-03-02

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