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Copper-based electrodes for IT-SOFC
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2018-03-02 , DOI: 10.1016/j.jeurceramsoc.2018.02.029
Francesca Zurlo , Alessandro Iannaci , Vincenzo M. Sglavo , Elisabetta Di Bartolomeo

Copper and gadolinium doped ceria (GDC) anode supported fuel cells were co-sintered at relatively low temperature (900 °C) and successfully tested in the intermediate temperature (IT) range. The GDC electrolyte densification was promoted by a compressive strain induced by increasing the anodic thickness and was evaluated by SEM investigation. Instead of more commonly used La0.8Sr0.2Fe0.6Co0.4O3-δ, strontium and copper-doped lanthanum ferrite La0.8Sr0.2Fe0.8Cu0.2O3-δ (LSFCu) mixed with 30 wt% GDC (LSFCu-GDC) was employed as cathodic material. Preliminary tests on Cu-GDC/GDC/LSFCu-GDC single cells showed promising results at temperature as low as 650 °C using hydrogen as fuel.



中文翻译:

用于IT-SOFC的铜基电极

铜和g掺杂的二氧化铈(GDC)阳极支撑的燃料电池在相对较低的温度(900°C)下共烧结,并在中间温度(IT)范围内成功进行了测试。GDC电解质的致密化是通过增加阳极厚度引起的压缩应变来促进的,并通过SEM研究对其进行了评估。锶和掺杂铜的镧铁氧体代替了更常用的La 0.8 Sr 0.2 Fe 0.6 Co 0.4 O3 -δLa 0.8 Sr 0.2 Fe 0.8 Cu 0.2 O3 (LSFCu)与30重量%GDC(LSFCu-GDC)混合用作阴极材料。对Cu-GDC / GDC / LSFCu-GDC单电池的初步测试显示,在低至650°C的温度下,使用氢气作为燃料的结果令人鼓舞。

更新日期:2018-03-02
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