Metal-Free Carbocatalysis in Advanced Oxidation Reactions,Accounts of Chemical Research

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Metal-Free Carbocatalysis in Advanced Oxidation Reactions
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2018-03-01 00:00:00 , DOI: 10.1021/acs.accounts.7b00535
Xiaoguang Duan ₁ , Hongqi Sun ₂ , Shaobin Wang ₁

Affiliation

Catalytic processes have remarkably boosted the rapid industrializations in chemical production, energy conversion, and environmental remediation. As one of the emerging applications of carbocatalysis, metal-free nanocarbons have demonstrated promise as catalysts for green remediation technologies to overcome the poor stability and undesirable metal leaching in metal-based advanced oxidation processes (AOPs). Since our reports of heterogeneous activation of persulfates with low-dimensional nanocarbons, the novel oxidative system has raised tremendous interest for degradation of organic contaminants in wastewater without secondary contamination. In this Account, we showcase our recent contributions to metal-free catalysis in advanced oxidation, including design of nanocarbon catalysts, exploration of intrinsic active sites, and identification of reactive species and reaction pathways, and we offer perspectives on carbocatalysis for future environmental applications.

中文翻译：

高级氧化反应中的无金属碳催化

催化过程极大地促进了化学生产，能量转换和环境修复方面的快速工业化。作为碳催化的新兴应用之一，无金属的纳米碳已被证明是绿色修复技术的催化剂，有望克服基于金属的高级氧化工艺（AOP）中的不良稳定性和不良的金属浸出。自从我们报导了低维纳米碳对过硫酸盐的异质活化以来，新型的氧化系统引起了人们对无二次污染的废水中有机污染物降解的极大兴趣。在此帐户中，我们展示了我们最近对高级氧化中的无金属催化的贡献，包括纳米碳催化剂的设计，固有活性位点的探索，

更新日期：2018-03-01

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