With α-(pseudo)halo vinylphosphonate as the electrophilic coupling partner, a variety of alkyl- and benzylic zinc reagents underwent vinylation reactions to produce α-alkyl vinylphosphonates. This unprecedented Pd-catalysed Negishi coupling features mild reaction conditions, high functional group tolerance, broad substrate scope, retention of the olefin geometry, and easy gram-scale synthesis.

中文翻译：

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钯催化的α-卤代乙烯基膦酸酯和α-膦酰基乙烯基磺酸酯与烷基锌的偶联：α-烷基乙烯基膦酸酯的直接，通用的合成†

以α-（伪）卤代乙烯基膦酸酯为亲电子偶合体，各种烷基锌和苄基锌试剂进行乙烯基化反应以生成α-烷基乙烯基膦酸酯。这种前所未有的Pd催化的Negishi偶联具有温和的反应条件，较高的官能团耐受性，宽泛的底物范围，保留了烯烃的几何形状以及容易的克级合成。