A Versatile Reagent and Method for Direct Aliphatic Sulfonylation,Advanced Synthesis & Catalysis

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A Versatile Reagent and Method for Direct Aliphatic Sulfonylation
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-03-12 , DOI: 10.1002/adsc.201800071
Andre Shavnya ₁ , Kevin D. Hesp ₁ , Andy S. Tsai ₁

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An efficient methodology has been developed for the two‐step synthesis of aliphatic sulfinate salts, sulfonamides, sulfonyl fluorides, and unsymmetrical sulfones on the basis of alkylation of a new versatile sulfonylating reagent. The new reagent is easily accessible in one step; the developed protocols are conducted under mild conditions and have a broad substrate scope.

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