CO2 Binding and Splitting by Boron–Boron Multiple Bonds,Angewandte Chemie International Edition

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CO2 Binding and Splitting by Boron–Boron Multiple Bonds
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-04-14 , DOI: 10.1002/anie.201802117
Andreas Stoy _{1,

2} , Julian Böhnke _{1,

2} , J. Oscar C. Jiménez-Halla ₃ , Rian D. Dewhurst _{1,

2} , Torsten Thiess _{1,

2} , Holger Braunschweig _{1,

2}

Affiliation

The room‐temperature, ambient‐pressure reactions of CO₂ with two species containing boron–boron multiple bonds led to the incorporation of either one or two CO₂ molecules. The structural characterization of a thermally unstable intermediate in one case indicates that an initial [2+2] cycloaddition is the key step in the reaction mechanism.

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