Zinc and bimetallic zinc-nickel catalysts for acetylene acetoxylation were prepared with Zn(OAc)₂·2H₂O and Ni(OAc)₂·4H₂O as precursors, and characterized by ICP-AES, BET, XPS, TEM, TPD-MS and TG. The catalytic performances of the obtained Zn-Ni/AC catalysts were tested in a fixed-bed reactor. The results indicated that the addition of nickel decreased the size of Zn(OAc)₂ particles and inhibited carbon deposition on the catalyst surface; there was a synergistic effect between the two metal components, which modified the electronic properties of Zn(OAc)₂ particles and modulated the catalytic adsorption of acetylene and acetic acid, thereby enhancing the activity and stability of the zinc catalysts.

以Zn（OAc）₂ ·2H ₂ O和Ni（OAc）₂ ·4H ₂ O为前驱体制备了用于乙炔乙氧基化的锌和双金属锌镍催化剂，并通过ICP-AES，BET，XPS，TEM，TPD- MS和TG。在固定床反应器中测试了所获得的Zn-Ni / AC催化剂的催化性能。结果表明，镍的加入减少了Zn（OAc）₂颗粒的尺寸并抑制了碳在催化剂表面的沉积。两种金属成分之间存在协同效应，从而改变了Zn（OAc）₂的电子性能 并调节乙炔和乙酸的催化吸附，从而增强锌催化剂的活性和稳定性。