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Clean synthesis gas production from municipal solid waste via catalytic gasification and reforming technology
Catalysis Today ( IF 5.2 ) Pub Date : 2018-02-27 , DOI: 10.1016/j.cattod.2018.02.050
Lu Zhang , Wei Wu , Yongjie Zhang , Xianchao Zhou

In this paper, the municipal solid waste was used as raw material to produce clean synthesis gas via catalytic gasification and reforming technology and gas purification unit. Nickel based catalysts with different Ce content were prepared by impregnation, then the effects of operating parameters including the oxygen addition, steam addition and Ni-based catalysts’ component on synthesis gas generation characteristics were studied. The results indicated that the increasing of oxygen injection and steam supply can improve the carbon conversion efficiency and cold gas efficiency. The addition of metal additives in Ni-based catalyst can promote the decomposition of tar and increase synthesis gas yield. At the temperature of 850 °C, equivalence ratio = 0.06, steam/carbon ratio = 3.6, the clean synthesis gas was produced with hydrogen concentration of 36.78 vol.% and carbon monoxide concentration of 15.29 vol.% via catalytic gasification and reforming process. The cold gas efficiency and carbon conversion rate were 70.17% and 87.17%, respectively. The yield of syngas was up to 0.679 m3/kg and the tar content was reduced to 17.76 g/Nm3. After the purification of the gas purification unit, the phenolic compounds were completely removed. The content of SO2 and NOX gas can meet the emission standard of air pollutants, and the average removal efficiency of heavy metal Cr, Pb, Zn, Cu and Hg was above 50%.



中文翻译:

通过催化气化和重整技术从城市固体废物中清洁生产合成气

本文以城市生活垃圾为原料,通过催化气化重整技术和气体净化装置生产清洁的合成气。通过浸渍法制备了不同铈含量的镍基催化剂,研究了氧,水蒸气和镍基催化剂组成等操作参数对合成气生成特性的影响。结果表明,增加注氧量和蒸汽供应量可以提高碳转化效率和冷气效率。在镍基催化剂中添加金属添加剂可以促进焦油的分解并提高合成气的收率。在850°C的温度下,当量比= 0.06,蒸汽/碳比= 3.6,通过催化气化和重整工艺生产的清洁合成气的氢气浓度为36.78%(体积),一氧化碳浓度为15.29%(体积)。冷气效率和碳转化率分别为70.17%和87.17%。合成气产量高达0.679 m3 / kg,并且焦油含量降低至17.76g / Nm 3。在气体净化单元的净化之后,酚类化合物被完全去除。SO 2和NO X气体的含量可以满足大气污染物的排放标准,重金属Cr,Pb,Zn,Cu和Hg的平均去除率在50%以上。

更新日期:2018-02-27
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