In this study, a novel system comprising metalloporphyrins and cyclohexene for the biomimetic aerobic oxidation of toluene and its derivatives was developed, which exhibited relatively benign reaction conditions, good catalytic activity, and broad substrate scope. Based on a series of in situ EPR (Electron Paramagnetic Resonance) and UV–vis experiments, the effect of cyclohexene on the reaction and the catalytic mechanism were preliminarily investigated.

中文翻译：

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包含金属卟啉和环己烯的新型系统，用于仿生需氧氧化甲苯

在这项研究中，开发了一种新的系统，该系统包含金属卟啉和环己烯用于甲苯及其衍生物的仿生需氧氧化，表现出相对良好的反应条件，良好的催化活性和广泛的底物范围。基于一系列原位EPR（电子顺磁共振）和UV-vis实验，初步研究了环己烯对反应的影响和催化机理。