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Photocatalytic activity of TiO2/Nb2O5/PANI and TiO2/Nb2O5/RGO as new nanocomposites for degradation of organic pollutants
Journal of Hazardous Materials ( IF 12.2 ) Pub Date : 2018-02-26 , DOI: 10.1016/j.jhazmat.2018.02.052
Saviz Zarrin , Felora Heshmatpour

In this study, highly active titanium dioxide modified by niobium oxide (Nb2O5), polymer (PANI) and reduced graphene oxide (RGO) were successfully prepared. The morphology, structure, surface area and light absorption properties of the present nanocomposites for removal of methylene blue (MB) and methyl orange (MO) were investigated and compared with those of TiO2/Nb2O5 and TiO2 nanoparticles. The characterization techniques such as XRD, FT-IR, UV-Vis, SEM, EDX, BET and TEM were employed in order to identify the nanocomposites. Also, photocatalytic properties of TiO2/Nb2O5/PANI and TiO2/Nb2O5/RGO nanocomposites under visible light irradiation were studied. In this way, the obtained results were compared to each other and also compared to TiO2/Nb2O5 and TiO2 nanoparticles. In this context, the chemical oxygen demand (COD) removal follows the photodegradation in observed performance. The results indicate that reduced TiO2/Nb2O5 nanocomposite is effectively modified by graphene oxide to give TiO2/Nb2O5/RGO composite. The TiO2/Nb2O5/RGO exhibits significantly higher photocatalytic activity in degradation of organic dyes under visible light rather than that of TiO2/Nb2O5/PANI, TiO2/Nb2O5 and pure TiO2.



中文翻译:

TiO 2 / Nb 2 O 5 / PANI和TiO 2 / Nb 2 O 5 / RGO作为新型纳米复合材料降解有机污染物的光催化活性

在这项研究中,成功制备了由氧化铌(Nb 2 O 5),聚合物(PANI)和还原型氧化石墨烯(RGO)改性的高活性二氧化钛。研究了用于去除亚甲基蓝(MB)和甲基橙(MO)的本纳米复合材料的形态,结构,表面积和光吸收性质,并将其与TiO 2 / Nb 2 O 5和TiO 2纳米粒子的形态,结构,表面积和光吸收性质进行了比较。为了鉴定纳米复合材料,采用了XRD,FT-IR,UV-Vis,SEM,EDX,BET和TEM等表征技术。此外,TiO 2 / Nb 2 O 5 / PANI和TiO 2的光催化性能研究了可见光下的/ Nb 2 O 5 / RGO纳米复合材料。以这种方式,将获得的结果彼此进行比较,并且还与TiO 2 / Nb 2 O 5和TiO 2纳米颗粒进行比较。在这种情况下,化学需氧量(COD)的去除遵循观察到的性能中的光降解。结果表明,氧化石墨烯可以有效地还原还原的TiO 2 / Nb 2 O 5纳米复合材料,得到TiO 2 / Nb 2 O 5 / RGO复合材料。TiO 2 / Nb 2 O 5/ RGO在可见光下对有机染料的降解表现出比TiO 2 / Nb 2 O 5 / PANI,TiO 2 / Nb 2 O 5和纯TiO 2更高的光催化活性。

更新日期:2018-02-27
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